catena-Poly[[[bis(1,10-phenanthroline-κ2 N,N′)manganese(II)]-μ-2,2′-dithiodibenzoato-κ2 O,O] methanol hemisolvate monohydrate]
نویسندگان
چکیده
The title complex, {[Mn(C(14)H(8)O(4)S(2))(C(12)H(8)N(2))(2)]·0.5CH(3)OH·H(2)O}(n), has a one-dimensional chain structure in which the Mn(II) atom is six-coordinated by four N atoms from two 1,10-phenanthroline (phen) ligands and two O atoms from two 2,2'-dithio-dibenzoate (L) ligands. The L ligands adopt a bis-(monodentate) (syn-anti) coordination mode and bridge adjacent Mn(II) centres, generating a chain running along [201]. Adjacent chains are linked into a two-dimensional network, parallel to (10), via inter-chain C-H⋯π and π-π stacking [centroid-centroid distance = 3.477 (1) Å] inter-actions. The structure also contains numerous hydrogen-bonding interactions, which further link the two-dimensional entities into a three-dimensional supramolecular network.
منابع مشابه
catena-Poly[[[aqua(formato-κO)(1,10-phenanthroline-κ2 N,N′)manganese(II)]-μ-formato-κ2 O:O′] monohydrate]
The title compound, {[Mn(HCOO)(2)(C(12)H(8)N(2))(H(2)O)]·H(2)O}(n), consists of polymeric chains of the complex [Mn(HCOO)(2)(phen)(H(2)O)](∞) (phen is 1,10-phenanthroline) with solvent water mol-ecules. The chains contain six-coordinate Mn(II) ions bridged by formate anions. They are further extended into a three-dimensional network via O-H⋯O hydrogen-bonding inter-actions and inter-chain π-π s...
متن کاملcatena-Poly[[[diaqua(1,10-phenanthroline-κ2 N,N′)zinc]-μ-4,4′-bipyridine-κ2 N:N′] dinitrate 4,4′-bipyridine hemisolvate monohydrate]
In the title compound, [Zn(C(10)H(8)N(2))(C(12)H(8)N(2))(H(2)O)(2)](NO(3))(2)·0.5C(10)H(8)N(2)·H(2)O, the Zn(II) atom is coordinated in a distorted octa-hedral geometry by two N atoms from two 4,4'-bipyridine (4,4'-bipy) ligands, two N atoms from a chelating 1,10-phenanthroline ligand and two O atoms from two mutually cis water mol-ecules. The 4,4'-bipy ligands bridge the Zn(II) atoms into a ch...
متن کاملcatena-Poly[[[aqua(1,10-phenanthroline-κ2 N,N′)zinc]-μ-acetylenedicarboxylato-κ2 O 1:O 2] monohydrate]
In the title complex, {[Zn(C₄O₄)(C₁₂H₈N₂)(H₂O)]·H₂O}(n), the penta-coordinated Zn(II) ion is bound to two N atoms of the 1,10-phenanthroline ligand, two O atoms from two bridging acetyl-enedicarboxyl-ate anions and a water O atom in a distorted trigonal-bipyramidal geometry. The crystal structure is characterized by polymeric zigzag chains running parallel to [2-10] and is stabilized by O-H⋯O h...
متن کاملTetrakis(μ-phenoxyacetato-κ2 O:O′)bis[(1,10-phenanthroline-κ2 N,N′)manganese(II)] methanol hemisolvate
The title complex, [Mn(2)(C(8)H(7)O(3))(4)(C(12)H(8)N(2))(2)]·0.5CH(3)OH, is a carboxyl-ate-bridged dinuclear Mn(II) complex with four phenoxy-acetate ions and two 1,10-phenanthroline mol-ecules as ligands. Each of the four phenoxy-acetate anions bridges the pair of Mn atoms. The asymmetric unit is completed by a half-occupancy methanol solvent mol-ecule. Face-to-face π-π stacking inter-actions...
متن کاملcatena-Poly[[[bis(1,10-phenanthroline-κ2 N,N′)manganese(II)]-μ-9,10-dioxoanthracene-1,5-disulfonato-κ2 O 1:O 5] tetrahydrate]
The title complex, {[Mn(C(14)H(6)O(8)S(2))(C(12)H(8)N(2))(2)]·4H(2)O}(n), exhibits a chain-like polymeric structure with 9,10-dioxo-anthracene-1,5-disulfonate anions bridging Mn(II) atoms in a bis-monodentate mode. The unique Mn(II) atom is located on a crystallographic centre of inversion. Four N atoms from two chelating 1,10-phenanthroline ligands and two sulfonate O atoms from two symmetry-r...
متن کامل